Quantitative Aspects: The Mole

30 min
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Atoms are far too small and numerous to count one by one, so chemists count them in a big fixed bundle called the mole (mol).

  • One mole is 6,022×10236{,}022 \times 10^{23} particles (Avogadro's number) — just as 'a dozen' always means 12.
  • The molar mass (MM) of a substance is the mass of one mole, in grams per mole (g⋅mol1\text{g·mol}^{-1}). You read it off the periodic table: carbon is 12 g⋅mol112\ \text{g·mol}^{-1}; for a compound, add up the atoms — water H2O\text{H}_2\text{O} is 2(1)+16=18 g⋅mol12(1) + 16 = 18\ \text{g·mol}^{-1}.

The key formula links number of moles (nn), mass (mm) and molar mass (MM):

n=mMn = \frac{m}{M}

Worked example: how many moles are in 36 g36\ \text{g} of water? n=3618=2 moln = \frac{36}{18} = 2\ \text{mol}.

The molar mass of water is 18 g⋅mol118\ \text{g·mol}^{-1}. How many moles are in 54 g54\ \text{g} of water?

Carbon has a molar mass of 12 g⋅mol112\ \text{g·mol}^{-1}. What is the mass (in grams) of 2 mol2\ \text{mol} of carbon?

Approximately how many particles are in one mole of any substance?